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πŸ§ͺ The pH Scale and Neutralisation

Spec 5.4.2.4 πŸ“™ Higher
πŸ“– In-Depth Theory

The pH Scale

The pH SCALE measures the CONCENTRATION of hydrogen ions (H⁺) in a solution β€” it indicates how acidic or alkaline a solution is.
Scale range: 0 to 14 (though values slightly outside this range are possible).
pH 0–6: ACIDIC (more H⁺ ions than OH⁻ ions)
pH 7: NEUTRAL (equal H⁺ and OH⁻ β€” pure water at 25Β°C)
pH 8–14: ALKALINE (more OH⁻ ions than H⁺ ions)
The pH scale is LOGARITHMIC β€” each unit change represents a 10Γ— change in H⁺ concentration:
pH 3 has 10Γ— more H⁺ than pH 4.
pH 3 has 100Γ— more H⁺ than pH 5.
Typical pH values:
Hydrochloric acid (conc.): pH ~0–1
Vinegar (ethanoic acid): pH ~3
Coffee: pH ~5
Pure water: pH 7
Baking soda solution: pH ~9
Sodium hydroxide solution: pH ~13–14

Indicators and Measuring pH

An INDICATOR is a substance that changes colour depending on the pH of a solution.
UNIVERSAL INDICATOR:
A mixture of indicators that shows a range of colours across the pH scale.
Red β†’ orange β†’ yellow β†’ green β†’ blue β†’ purple as pH increases from 0 to 14.
Gives an APPROXIMATE pH β€” tells you the pH range.
LITMUS:
Red in ACID, blue in ALKALI, purple in neutral.
Simple test β€” tells you acid or alkali, not the pH number.
PHENOLPHTHALEIN:
Colourless in acid, PINK in alkali.
Used in titrations β€” clear colour change at the end point.
pH PROBE / METER:
Gives a PRECISE numerical pH reading β€” more accurate than indicators.
Used in industry and for accurate laboratory measurements.
THE RELATIONSHIP BETWEEN pH AND CONCENTRATION:
The MORE H⁺ ions in solution β†’ LOWER pH (more acidic).
The MORE OH⁻ ions in solution β†’ HIGHER pH (more alkaline).
Adding water DILUTES the solution β†’ concentration of H⁺ decreases β†’ pH INCREASES towards 7.

Effect of Neutralisation on pH

Adding a BASE to an ACID gradually increases the pH (makes it less acidic).
Adding an ACID to an ALKALI gradually decreases the pH (makes it less alkaline).
A TITRATION CURVE shows how pH changes as acid is added to alkali:
At the START: pH high (~13) β€” the solution is strongly alkaline.
As acid is added: pH falls slowly at first.
Near the END POINT: pH drops RAPIDLY β€” a large pH change for a small addition.
At the END POINT: pH = 7 (if strong acid + strong alkali).
After the end point: pH continues to fall as excess acid is added.
WHY SUCH A SHARP CHANGE NEAR THE END POINT:
Near the equivalence point, there is very little OH⁻ left to absorb the H⁺ from the added acid.
So each small addition of acid produces a large change in H⁺ concentration β†’ large pH change.
⚠️ Common Mistake

Lower pH = MORE ACIDIC = MORE H⁺ ions. Higher pH = MORE ALKALINE = FEWER H⁺ ions (more OH⁻). Students often confuse pH 2 and pH 12 β€” pH 2 is strongly acidic, pH 12 is strongly alkaline. pH 7 is neutral β€” pure water. NOT all solutions at pH 7 are water.

πŸ“Œ Key Note

pH 0–6: acidic. pH 7: neutral. pH 8–14: alkaline. Lower pH = more H⁺ ions. pH scale is logarithmic β€” each unit = 10Γ— change in H⁺. Universal indicator: shows range of colours. Phenolphthalein: colourless in acid, pink in alkali. pH meter: most accurate.

🎯 Matching Activity β€” Match the pH to the Description

Match each pH value to the correct description. β€” drag the symbols on the right to match the component names on the left.

pH 1
Drop here
pH 7
Drop here
pH 13
Drop here
pH 4
Drop here
pH 10
Drop here
Weakly acidic β€” e.g. black coffee or tomato juice
Strongly alkaline β€” high concentration of OH⁻ ions
Neutral β€” equal H⁺ and OH⁻ ions β€” pure water at 25Β°C
Weakly alkaline β€” e.g. baking soda solution
Strongly acidic β€” high concentration of H⁺ ions
⭐ Higher Tier Only

Strong acids fully dissociate (HCl β†’ H⁺ + Cl⁻) β€” maximum H⁺ at given concentration. Weak acids partially dissociate (CH₃COOH β‡Œ CH₃COO⁻ + H⁺) β€” less H⁺ at same concentration β†’ higher pH. Strong acid and weak acid at same concentration: strong acid has lower pH. Strong β‰  concentrated.

🎯 Test Yourself
Question 1 of 2
1. A solution has a pH of 2. Another has a pH of 4. How do their H⁺ ion concentrations compare?
2. An acid is diluted by adding water. What happens to its pH?
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